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Beilstein J. Org. Chem. 2010, 6, No. 57, doi:10.3762/bjoc.6.57
Graphical Abstract
Scheme 1: Synthesis of oligoPPEs by a unidirectional (a) or bidirectional (b) repeating unit by repeating uni...
Scheme 2: Three divergent-convergent routes to oligoPPEs. R denotes solubilising substituents such as hexyl.
Scheme 3: Synthesis of the building blocks 11, 21, and 31. The depicted alkene configuration of 5 was chosen ...
Scheme 4: Carbometalation, an occasionally detected side reaction. The depicted alkene configuration was chos...
Scheme 5: Iodination of 1,4-dihexylbenzene.
Scheme 6: Different routes to compound 14, a representative of the large group of functionalized oligoPPEs.